Voluntary \Vol"un*ta*ry\, n.; pl. {Voluntaries}. 1. One who engages in any affair of his own free will; a volunteer. [R.] --Shak. 2. (Mus.) A piece played by a musician, often extemporarily, according to his fancy; specifically, an organ solo played before, during, or after divine service. 3. (Eccl.) One who advocates voluntaryism.